Potassium dichromate in perchloric acid is very suitable for checking the photometric accuracy of spectrophotometers. In the UV range, the Potassium dichromate spectrum has characteristic maxima at 257 nm and 350 nm and characteristic minima at 235 nm and 313 nm. The spectrum reaches a plateau at 430 nm, which is used to determine photometric accuracy in the visible range.
Hellma Analytics purchases the reference material for this filter directly from NIST (SRMR 935a “Potassium Dichromate”). The filter solutions are manufactured in strict compliance with NIST requirements and filled under controlled conditions. The cuvettes are then immediately fused to become airtight.
Typical spectrum of a Potassium dichromate solution with 60 mg/l measured at a slit width of 2 nm.
Type | Art.-No. | 235 nm | 257 nm | 313 nm | 350 nm |
---|---|---|---|---|---|
UV20 | 667020 | 0.25 | 0.29 | 0.10 | 0.22 |
UV40 | 667040 | 0.50 | 0.57 | 0.20 | 0.43 |
UV60 | 667060 | 0.75 | 0.86 | 0.30 | 0.65 |
UV80 | 667080 | 1.00 | 1.16 | 0.40 | 0.86 |
UV0100 | 6670100 | 1.25 | 1.45 | 0.50 | 1.07 |
UV0120 | 6670120 | 1.50 | 1.75 | 0.60 | 1.28 |
UV0140 | 6670140 | 1.75 | 2.05 | 0.70 | 1.50 |
UV0160 | 6670160 | 2.00 | 2.35 | 0.80 | 1.70 |
UV0180 | 6670180 | 2.25 | 2.65 | 0.90 | 1.90 |
UV0200 | 6670200 | 2.50 | 2.95 | 1.00 | 2.10 |
Type | Article-No. | Content |
---|---|---|
UV20 | 667020 | 20 mg/l Potassium dichromate in HClO4, (0.1 – 0.3 Abs) |
UV40 | 667040 | 40 mg/l Potassium dichromate in HClO4, (0.2 – 0.6 Abs) |
UV60 | 667060 | 60 mg/l Potassium dichromate in HClO4, (0.3 – 0.9 Abs) |
UV80 | 667080 | 80 mg/l Potassium dichromate in HClO4, (0.4 – 1.2 Abs) |
UV0100 | 6670100 | 100 mg/l Potassium dichromate in HClO4, (0.5 – 1.5 Abs) |
UV0120 | 6670120 | 120 mg/l Potassium dichromate in HClO4, (0.6 – 1.8 Abs) |
UV0140 | 6670140 | 140 mg/l Potassium dichromate in HClO4, (0.7 – 2.0 Abs) |
UV0160 | 6670160 | 160 mg/l Potassium dichromate in HClO4, (0.8 – 2.3 Abs) |
UV0180 | 6670180 | 180 mg/l Potassium dichromate in HClO4, (0.9 – 2.6 Abs) |
UV0200 | 6670200 | 200 mg/l Potassium dichromate in HClO4, (1.0 – 3.0 Abs) |
UV600 | 667600 | 600 mg/l Potassium dichromate in HClO4, (1.0 Abs at 430 nm) |
UV14 | 667014 | Perchloric acid (HClO4), reference filter |
Standard Measurement | UV20 – UV0200 Wavelengths: 235, 257, 313, 350 nm Slit width: 2 nm; with DAkkS calibration certificate |
---|---|
Standard Measurement | UV600 Wavelength: 430 nm Slit width: 2 nm; with DAkkS calibration certificate |
Possible Measurements | Wavelength: fix Slit width: 1 and 2 nm |
As the filters are measured individually, measurement results are free from systematic errors made when preparing solutions and with regards to the optical path length of the cuvette. The measurement values of reference filter UV14 (perchloric acid measured against an air blank) appear separately on the calibration certificate. To check absorbance linearity, take measurements using Potassium dichromate filters with different concentrations. Plot the absorbance values measured for each filter and wavelength against the measurement values that appear on the calibration certificate in a graph.